What is the electronic geometry and bond angle for CH4?

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Study for the MCAT Chemical and Physical Foundations of Biological Systems Exam. Practice with multiple choice questions, each with detailed explanations and hints. Excel in your exam and achieve your target score!

In the case of methane (CH4), the molecule exhibits a tetrahedral electronic geometry. This is determined by the presence of four bonding pairs of electrons surrounding the central carbon atom. Each hydrogen atom forms a single covalent bond with the carbon, utilizing all four valence electrons of carbon.

The arrangement of these four bonding pairs leads to a three-dimensional configuration that minimizes the repulsion between these electron pairs, consistent with VSEPR (Valence Shell Electron Pair Repulsion) theory. The ideal bond angle for a tetrahedral geometry is approximately 109.5 degrees. This angle arises because the electron pairs orient themselves in such a way to be as far apart from each other as possible, achieving maximum spatial separation.

Other options describe different molecular geometries which do not apply to methane:

  • A linear structure would indicate the presence of two bonding pairs and hence a bond angle of 180°, which does not represent CH4.
  • A trigonal planar arrangement, which typically involves three bonding pairs and a bond angle of 120°, is also not relevant because methane has four bonding pairs.
  • A trigonal bipyramidal geometry involves five bonding pairs with distinct bond angles of 90° and 120°, again not applicable to CH4.

Therefore

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